Gelation: Grow with the flow.
نویسنده
چکیده
381 news & views two ferromagnetic layers. In the present case, this is the ferroelectric BaTiO 3 sandwiched between magnetic Fe and La 0.67 Sr 0.33 MnO 3 layers. Indeed, theoretical calculations 6 have predicted the possibility of significant changes in the interfacial magnetization and spin polarization in a ferromagnet in response to the ferroelectric polarization state across the interface. Thus, the interplay between the non-volatile polarization states of the ferroelectric and its influence on the spin polarization can lead to unusual tunnelling characteristics. This is the focus of the paper by Garcia and co-workers. Using a combination of epitaxial synthesis, scanned probe imaging and high-resolution electron microscopy, they have demonstrated a large tunnelling magnetoresistance that is sensitive to the polarization state of the ferroelectric. The fundamental origin of this large effect arises from the asymmetric screening of the polarization at the two interfaces, albeit at a low temperature of 4.2 K. So, what are the implications of this approach? It is now becoming increasingly clear that ferromagnetism, and thus spin polarization, can be controlled and manipulated through a coupling of a magnetic layer to a ferroelectric or a multiferroic. Thus, more than one possible pathway to control magnetism with an electric field exists. Clearly, room-temperature operation is a critical step, although it is probable that that issue will be solved in the near future. However, an aspect that clearly emerges from this work, as well as from previous studies involving the manganites, is the observation that they are not the ideal candidates for room-temperature devices as the transfer of spin polarization at the interface invariably is corrupted. Thus, the discovery of alternative ferromagnets would be a fruitful future research direction to pursue. If using epitaxial oxide heterostructures is a possible pathway, the possibility of using the orbital degree of freedom in oxides as an active component of their interface interactions can also be a fertile area of research. Some initial results in this direction are already available. The robustness of these interactions, particularly with respect to electric-field cycling, long-term stability and speed of operation are all issues that need to be addressed for real-world devices. Finally, by far the most important issue will probably be this: what are the device structures and applications that will be enabled by these new observations? In summary, the paper by Garcia and co-workers has demonstrated, in a convincing way, the great potential of …
منابع مشابه
Effect of Inorganic Polymer Gel Systems on Residual Resistance Factor in Fractured Core Model
Excessive water production through fractures become an important problem in oil exploration of fractured reservoirs. For this purpose, polymer gels were prepared by crosslinking of aqueous solutions of polymer and crosslinker for the purpose of water management in high water cut fractured reservoirs. A copolymer of sulfonated polyacrylamide was used as polymer and chromium triacetate (Cr(OA...
متن کاملEffect of addition of ethyl alcohol on gelation and viscoelasticity of tissue conditioners.
The clinical effectiveness of tissue conditioners is influenced by their gelation characteristics and viscoelastic properties after gelation. The purpose of this study was to evaluate the effect of addition of ethyl alcohol (EtOH) on these properties, and to compare the effect of EtOH with that of the powder/liquid (P/L) ratio. Three tissue conditioners were used in this study. The gelation tim...
متن کاملFluctuations in chemical gelation.
We study a chemical gelation model in two dimensions which includes both monomer aggregations and bond fluctuations. Our numerical simulation shows that a sol-gel transition occurs when an initial monomer concentration is above a critical concentration. Fractal aggregates grow until the sol-gel transition occurs. After the gelation, however, bond fluctuations break the fractal structure and an ...
متن کاملDynamical arrest in attractive colloids: the effect of long-range repulsion.
We study gelation in suspensions of model colloidal particles with short-ranged attractive and long-ranged repulsive interactions by means of three-dimensional fluorescence confocal microscopy. At low packing fractions, particles form stable equilibrium clusters. Upon increasing the packing fraction the clusters grow in size and become increasingly anisotropic until finally associating into a f...
متن کاملRheological and structural properties of aqueous alginate during gelation via the Ugi multicomponent condensation reaction.
Turbidity, structure, and rheological features during gelation via the Ugi multicomponent condensation reaction of semidilute solutions of alginate have been investigated at different polymer and cross-linker concentrations and reaction temperatures. The gelation time of the system decreased with increasing polymer and cross-linker concentrations, and a temperature rise resulted in a faster gel...
متن کاملFormulation of Ibuprofen Beads by Ionotropic Gelation
Microencapsulation has become a common technique in the production of controlled release dosage forms. Many results have been reported, concerning the use of alginate beads as controlled release drug formulations. Alginate has a unique gel-forming property in the presence of multivalent cations, in an aqueous medium. Ibuprofen is an excellent analgesic and antipyretic, non-steroidal anti-inflam...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Nature materials
دوره 9 5 شماره
صفحات -
تاریخ انتشار 2010